A novel kind of shape memory polyurethane (SMPU) nanofibers with core-shell nanostructure is fabricated using coaxial electrospinning. Transmission electron microscopy (TEM) and scanning electron microscopy (SEM) results show that nanofibers with core-shell structure or bead-on-string structure can be electrospun successfully from the core solution of polycaprolactone based SMPU (CLSM... https://www.duospiritalis.com/